1-Rafael Nadal (ESP) v Qual. Marcos Daniel (BRA)
Igor Kunitsyn (RUS) v Teimuraz Gabashvili (RUS)
Denis Gremelmayr (GER) v Andrey Golubev (KAZ)
Lleyton Hewitt (AUS) v 26-Ivo Karlovic (CRO)
23-Robin Soderling (SWE) v Kevin Kim (USA)
Denis Istomin (UZB) v Qual. Santiago Giraldo (COL)
Qual. Ilia Bozoljac (SRB) v Nicolas Kiefer (GER)
Frederico Gil (POR) v 14-David Ferrer (ESP)
10-Nikolay Davydenko (RUS) v Stefan Koubek (AUT)
Diego Junqueira (ARG) v Paul Capdeville (CHI)
Nicolas Massu (CHI) v Daniel Koellerer (AUT)
Nicolas Devilder (FRA) v 17-Stanislas Wawrinka (SUI)
31-Nicolas Almagro (ESP) v Agustin Calleri (ARG)
Ernests Gulbis (LAT) v Sam Querrey (USA)
Qual. Peter Polansky (CAN) v Philipp Petzschner (GER)
Florent Serra (FRA) v 8-Fernando Verdasco (ESP)

3-Andy Murray (GBR) v Juan Ignacio Chela (ARG)
Mischa Zverev (GER) v Potito Starace (ITA)
Janko Tipsarevic (SRB) v Albert Montanes (ESP)
Qual. Franco Ferreiro (BRA) v 28-Feliciano Lopez (ESP)
18-Radek Stepanek (CZE) v Gaston Gaudio (ARG)
Yen-Hsun Lu (TPE) v Qual. Mathieu Montcourt (FRA)
Dudi Sela (ISR) v Qual. Jean-Rene Lisnard (MON)
Jan Hernych (CZE) v 13-Marin Cilic (CRO)
12-Fernando Gonzalez (CHI) v Qual. Jiri Vanek (CZE)
Qual. Rui Machado (POR) v Kristof Vliegen (BEL)
Marcel Granollers (ESP) v Josselin Ouanna (FRA)
Alexandre Sidorenko (FRA) v 20-Marat Safin (RUS)
30-Victor Hanescu (ROM) v Steve Darcis (BEL)
Mikhail Youzhny (RUS) v Gilles Muller (LUX)
Qual. Daniel Brands (GER) v Robert Kendrick (USA)
Wayne Odesnik (USA) v 7-Gilles Simon (FRA)

5-Juan Martin Del Potro (ARG) v Michael Llodra (FRA)
Viktor Troicki (SRB) v Qual. Lukasz Kubot (POL)
Thomaz Bellucci (BRA) v Martin Vassallo Arguello (ARG)
Qual. Fabio Fognini (ITA) v 25-Igor Andreev (RUS)
21-Dmitry Tursunov (RUS) v Arnaud Clement (FRA)
Fabrice Santoro (FRA) v Christophe Rochus (BEL)
Marcos Baghdatis (CYP) v Juan Monaco (ARG)
Julien Benneteau (FRA) 9-Jo-Wilfried Tsonga (FRA)
16-Tommy Robredo (ESP) v Adrian Mannarino (FRA)
Evgeny Korolev (RUS) v Daniel Gimeno-Traver (ESP)
Guillermo Garcia-Lopez (ESP) v Andreas Seppi (ITA)
Maximo Gonzalez (ARG) v 22-Mardy Fish (USA)
29-Philipp Kohlschreiber (GER) v Bernard Tomic (AUS)
Juan Carlos Ferrero (ESP) v Ivan Ljubicic (CRO)
Brian Dabul (ARG) v Qual. Sergiy Stakhovsky (UKR)
Nicolas Lapentti (ECU) v 4-Novak Djokovic (SRB)

6-Andy Roddick (USA) v Romain Jouan (FRA)
Oscar Hernandez (ESP) v Ivo Minar (CZE)
Ivan Navarro (ESP) v Andreas Beck (GER)
Marc Gicquel (FRA) v 27-Rainer Schuettler (GER)
24-Jurgen Melzer (AUT) v Sergio Roitman (ARG)
Guillaume Rufin (FRA) v Eduardo Schwank (ARG)
Qual. Victor Crivoi (ROU) v Qual. Simon Greul (GER)
Bobby Reynolds (USA) v 11-Gael Monfils (FRA)
15-James Blake (USA) v Qual. Leonardo Mayer (ARG)
Andrei Pavel (ROM) v Tommy Haas (GER)
Bjorn Phau (GER) v Jeremy Chardy (FRA)
Simone Bolelli (ITA) v 19-Tomas Berdych (CZE)
32-Paul-Henri Mathieu (FRA) v Laurent Recouderc (FRA)
Robby Ginepri (USA) v Pablo Andujar (ESP)
Jose Acasuso (ARG) v Qual. Santiago Ventura (ESP)
Alberto Martin (ESP) v 2-Roger Federer (SUI)